澜沧江某水电站右坝肩工程边坡倾倒变形问题的数值 模拟研究

澜沧江某水电站处于青藏高原东部边缘地带,属于高山峡谷地形地貌,高地应力环境,岩体卸荷裂隙很发育,使得倾倒变形和岩体质量、断裂活动及地震构造一样成为影响工程边坡岩体稳定的主要因素。针对工程边坡的大变形问题可采用离散元的数值模拟分析方法。通过建立理论开挖和工程边坡开挖离散元模型,可分别得出倾倒变形破坏机理发展过程为初期弱倾倒变形岩体的层内剪切错动、强倾倒变形岩体的层内拉张变形、强倾倒变形岩体的切层张-剪破裂及极强倾倒破裂岩体的折断张裂(坠覆)破裂和工程边坡的变形范围、确定开挖面及加固方式等。通过工程边坡模型的计算结果和现场地质调查成果的比较表明,计算结果和实际情况基本吻合。     

底摩擦重力试验在倾倒变形岩体稳定性研究中的应用

底摩擦重力试验(底摩擦试验)是利用相似理论分析原理,将研究原形按几何比例和各种物理力学参数,制作相似模型及确定相应的边界条件。然后按照相似边界条件进行加载试验,再现曾经发生过或今后将会出现的物理力学现象,进而了解其发展演化规律及其对工程的影响。澜沧江某水电站坝肩主要为典型的倾倒变形岩体,为探讨倾倒变形岩体在天然重力场条件的变形破裂发展趋势。试验采用模拟重力场条件的岩体底摩擦模型试验技术模拟分析岩体倾倒变形进一步发展演变过程及特征。     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.     

矿产预测中成矿信息的提取和强化

成矿信息的提取是矿产预测的重要手段,其方法的有效性直接影响到预测成果的可靠性。在成矿规律研究的基础上,有意识地干预模型的构成,突出与成矿有关的信息;抑制某些成矿意义不明显和属干扰的信息,有目的地使模型向反映成矿信息的方向逼近,提高模型与矿床实际赋存地质环境的吻合程度,均是成矿信息提取和强化的内涵。本文从研究实践中总结了先验约束模型和非先验约束模型的强化方法,在新疆阿勒泰地区的地质－找矿工作中已取得     

Intrinsic sample methods for mineral exploration and resource assessment

We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California.     

流体在岩浆型铬铁矿和铂族元素成矿过程中的作用及意义

镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。     

五大连池火山群新期火山渣丘成因的探讨

火山渣丘,是火山区内的一种特殊的地质现象,以前地其成因国内外尚无详细探讨和描述,有的学者曾经统称为副火山。笔者通过实地调查,对这一结论提出新的见解,认为火山渣丘的形成是一复杂的地质现象,其成因具有多元性。这对探讨火山喷发规律,对火山地质地貌的准确描述与具有积极作用。     

含煤层地质环境下地震波场的数值模拟

本文对含低速煤层地质环境下弹性波场多波多分量地震资料进行了二维数值模拟研究,对人工边界反射进行了有效处理,频散效应得到了有效的压制,对几种不同激发与观测排列方式下的弹性波资料进行了模型计算与分析。     

湘中“桃江式”锰矿含锰岩系的定量研究及其找矿意义

本文从分析地质体数学特征的思想出发,来研究“桃江式”锰矿的含矿母岩－“含锰岩系”的数学特征。含锰岩系主要由五种岩石组成：粘土岩、黑色页岩、条带状页岩、含锰灰岩和碳酸锰矿层,其数学特征研究包括其统计特征分析、结构特征分析和空间特征分析。文最后讨论了这些数学特征在寻找同类锰矿中的意义。